Researchers Crack the Recipe of Roman Concrete Mix

Where once pozzolanic material like volcanic ash was the key, turns out the secret to the durability of Roman concrete was quicklime and hot mixing.

Massachusetts Institute of Technology
Hot Mixing and Lime Key to Roman Concrete Durability
A large-area elemental map (Calcium: red, Silicon: blue, Aluminum: green) of a 2 cm fragment of ancient Roman concrete (right) collected from the archaeological site of Privernum, Italy (left). A calcium-rich lime clast (in red), which is responsible for the unique self-healing properties in this ancient material, is clearly visible in the lower region of the image.
Courtesy of the researchers | MIT

MIT published news – reportedly solving a riddle that’s questioned the construction culture for decades. Researchers from MIT, Harvard University, and laboratories in Italy and Switzerland have published their latest findings in the riddle behind the lifespan of Roman concrete.

The latest issue of Science Advances includes a paper by MIT professor of civil and environmental engineering Admire Masic; Linda Seymour, PhD; Janille Maragh, MIT; Paolo Sabatini, DMAT (Italy); Micel Di Tommaso, Instituto Meccanica dei Materiali in Switzerland; and James Weaver at the Wyss Institute for Biologically Inspired Engineering at Harvard University.

Hot Mixing and Lime Key to Roman Concrete DurabilityA calcium-rich lime clast (in red), which is responsible for the unique self-healing properties in this ancient material, is clearly visible in the lower region of the large-area elemental map (Calcium: red, Silicon: blue, Aluminum: green) of a 2 cm fragment of ancient Roman concrete.Courtesy of the researchers | MITUntil now, the assumption was “that the key to the ancient concrete’s durability was based on one ingredient: pozzolanic material such as volcanic ash from the area of Pozzuoli, on the Bay of Naples,” writes David Chandler, MIT News Office. Further cementing this assumption was the fact that the ash was shipped across the Roman empire for construction. Historians and architects went as far as to describe it as “a key ingredient for concrete.”

According to the latest research, the secret required a closer look.

Where they were once thought to be more of a mistake in the concrete mix, Masic wasn’t entirely convinced.

New insight via high-resolution multiscale imaging and chemical mapping techniques pointed against what was originally believed. Instead, the new hypothesis was whether or not the Romans utilized the more reactive quicklime. If so, the key to the durability of Roman concrete was hot mixing. This, according to Masic, would have reduced the curing and setting time and ultimately allowed a much faster construction.

Understandably, researchers are excited. (Aren’t we all? Really?) The team is working to commercialize the modified cement material, with Masic mentioning that “it could improve the durability of 3D-printed concrete.”

With the globe’s effort in reducing the carbon emissions and reaching Net-Zero concrete construction, cracking the code behind the durable Roman concrete might allow new mixes to be durable light-weight concrete.

Read the full announcement at news.MITedu.

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